Document Detail

3-Bromopenta-2,4-dienylsilane: a useful reagent for the preparation of [3]dendralenes and polycyclic compounds.
MedLine Citation:
PMID:  23314740     Owner:  NLM     Status:  Publisher    
Starting from ([Formula: see text]-1-trimethylsilyl-3-bromopenta-2,4-diene, a lithium-bromine exchange reaction followed by addition onto carbonyl compounds provided the corresponding dienyl alcohols. A Peterson-type [Formula: see text]-elimination promoted by a catalytic amount of trimethylsilyl triflate cross-conjugated gave triene systems ([3]dendralene) which rapidly reacted with the appropriate dienophiles to yield tandem intermolecular Diels-Alder cycloadducts.
Mohammed Rahif; Maryline Roux; Jérôme Thibonnet; Jean-Luc Parrain
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-1-12
Journal Detail:
Title:  Molecular diversity     Volume:  -     ISSN:  1573-501X     ISO Abbreviation:  Mol. Divers.     Publication Date:  2013 Jan 
Date Detail:
Created Date:  2013-1-14     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9516534     Medline TA:  Mol Divers     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Institut des Sciences Moléculaires de Marseille, Aix-Marseille Université, iSm2-UMR CNRS 6263, Campus scientifique de Saint Jérôme, Service 532, 13397 , Marseille Cedex 20, France.
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