| A 2E''-X2A2' transition of NO3 trapped in solid neon. | |
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MedLine Citation:
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PMID: 19957977 Owner: NLM Status: PubMed-not-MEDLINE |
Abstract/OtherAbstract:
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NO(3) has been stabilized in a neon matrix at 4.3 K in sufficient yield for detection of the absorptions between 7000 and 10,000 cm(-1), which arise from vibronically allowed transitions from the ground state to levels of the A (2)E'' state. The results confirm and somewhat extend previous gas-phase observations for (14)N(16)O(3). Additional spectra are presented for six other isotopologues of NO(3), four of which possess C(2v) symmetry. The splitting patterns for these species support the previous assignments. Alternations in the spacings of the nu(4) progression are consistent with the occurrence of weak to moderate Jahn-Teller interaction in the A 2E state of NO(3). |
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Authors:
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Marilyn E Jacox; Warren E Thompson |
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Publication Detail:
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Type: Journal Article |
Journal Detail:
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Title: The journal of physical chemistry. A Volume: 114 ISSN: 1520-5215 ISO Abbreviation: J Phys Chem A Publication Date: 2010 Apr |
Date Detail:
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Created Date: 2010-04-08 Completed Date: 2010-07-08 Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 9890903 Medline TA: J Phys Chem A Country: United States |
Other Details:
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Languages: eng Pagination: 4712-8 Citation Subset: - |
Affiliation:
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Optical Technology Division, National Institute of Standards and Technology, Gaithersburg, Maryland 20899-8441, USA. marilyn.jacox@nist.gov |
Export Citation:
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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