Document Detail


A 2E''-X2A2' transition of NO3 trapped in solid neon.
MedLine Citation:
PMID:  19957977     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Abstract/OtherAbstract:
NO(3) has been stabilized in a neon matrix at 4.3 K in sufficient yield for detection of the absorptions between 7000 and 10,000 cm(-1), which arise from vibronically allowed transitions from the ground state to levels of the A (2)E'' state. The results confirm and somewhat extend previous gas-phase observations for (14)N(16)O(3). Additional spectra are presented for six other isotopologues of NO(3), four of which possess C(2v) symmetry. The splitting patterns for these species support the previous assignments. Alternations in the spacings of the nu(4) progression are consistent with the occurrence of weak to moderate Jahn-Teller interaction in the A 2E state of NO(3).
Authors:
Marilyn E Jacox; Warren E Thompson
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  The journal of physical chemistry. A     Volume:  114     ISSN:  1520-5215     ISO Abbreviation:  J Phys Chem A     Publication Date:  2010 Apr 
Date Detail:
Created Date:  2010-04-08     Completed Date:  2010-07-08     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9890903     Medline TA:  J Phys Chem A     Country:  United States    
Other Details:
Languages:  eng     Pagination:  4712-8     Citation Subset:  -    
Affiliation:
Optical Technology Division, National Institute of Standards and Technology, Gaithersburg, Maryland 20899-8441, USA. marilyn.jacox@nist.gov
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