| 1H and 13C NMR assignments of all three isomeric o-fluoronaphthaldehydes and three o-fluorophenanthrene aldehydes. | |
| | |
MedLine Citation:
|
PMID: 19810003 Owner: NLM Status: MEDLINE |
Abstract/OtherAbstract:
|
Three isomeric o-fluoronaphthaldehydes, 9-fluorophenanthrene, and three previously unreported o-fluorophenanthrene aldehydes were analyzed in detail by multiple NMR techniques to provide unambiguous assignment of structures and resonances. The six aldehydes serve as the key starting materials for novel chiral ligands used in highly enantioselective rhodium-catalyzed asymmetric hydrogenation reactions. |
| | |
Authors:
|
Carl A Busacca; Scot Campbell; Nina C Gonnella; Chris H Senanayake |
Related Documents
:
|
20458403 - Aluminium-catalyzed intramolecular hydroamination of aminoalkenes. 17117873 - Enantioselective synthesis of diversely substituted quaternary 1,4-benzodiazepin-2-ones... 21897993 - Nickel-catalyzed sp(2) c-h bonds arylation of n-aromatic heterocycles with grignard rea... |
Publication Detail:
|
Type: Journal Article |
Journal Detail:
|
Title: Magnetic resonance in chemistry : MRC Volume: 48 ISSN: 1097-458X ISO Abbreviation: Magn Reson Chem Publication Date: 2010 Jan |
Date Detail:
|
Created Date: 2009-12-16 Completed Date: 2010-03-09 Revised Date: - |
Medline Journal Info:
|
Nlm Unique ID: 9882600 Medline TA: Magn Reson Chem Country: England |
Other Details:
|
Languages: eng Pagination: 74-9 Citation Subset: IM |
Copyright Information:
|
Copyright 2009 John Wiley & Sons, Ltd. |
Affiliation:
|
Department of Chemical Development, Boehringer-Ingelheim Pharmaceuticals, Inc., 900 Ridgebury Road, Ridgefield, CT 06877, USA. carl.busacca@boehringer-ingelheim.com |
Export Citation:
|
APA/MLA Format Download EndNote Download BibTex |
| MeSH Terms | |
Descriptor/Qualifier:
|
Aldehydes
/
chemistry* Carbon Isotopes Fluorine / chemistry* Hydrogen Isomerism Ligands Magnetic Resonance Spectroscopy Molecular Structure Naphthalenes / chemistry* Phenanthrenes / chemistry* |
| Chemical | |
Reg. No./Substance:
|
0/1-fluoronaphthaldehyde; 0/Aldehydes; 0/Carbon Isotopes; 0/Ligands; 0/Naphthalenes; 0/Phenanthrenes; 1333-74-0/Hydrogen; 66-77-3/1-naphthaldehyde; 7782-41-4/Fluorine; 85-01-8/phenanthrene |
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
Previous Document: Hemizygous Fabry disease associated with IgA nephropathy: a case report.
Next Document: High-performance affinity chromatography method for identification of l-arginine interacting factors...