Document Detail


(1)H- and (13)C-NMR analysis of a series of 1,2-diaryl-1H-4,5-dihydroimidazoles.
MedLine Citation:
PMID:  18007315     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
An analysis of the (1)H- and (13)C-NMR spectra of a series of 1,2-diaryl-1H-4,5-dihydroimidazoles and comparisons with 4,5-dihydroimidazoles having different substitution patterns are presented. The influence of different 1-aryl and 2-aryl group substituents on spectroscopic parameters of the heterocyclic ring and on the contributions of possible mesomeric structures in the system was determined. Spectroscopic features are coherent with the presence of two conjugated systems (Ar(1)-N and Ar(2)-C=N) which compete with the delocalization characteristics of the amidine system.
Authors:
Alejandra Salerno; Isabel A Perillo
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't     Date:  2005-02-28
Journal Detail:
Title:  Molecules (Basel, Switzerland)     Volume:  10     ISSN:  1420-3049     ISO Abbreviation:  Molecules     Publication Date:  2005  
Date Detail:
Created Date:  2007-11-16     Completed Date:  2008-01-29     Revised Date:  2009-10-27    
Medline Journal Info:
Nlm Unique ID:  100964009     Medline TA:  Molecules     Country:  Switzerland    
Other Details:
Languages:  eng     Pagination:  435-43     Citation Subset:  IM    
Affiliation:
Department of Organic Chemistry, Faculty of Pharmacy and Biochemistry, University of Buenos Aires, Junín 956 (1113), Buenos Aires, Argentina.
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MeSH Terms
Descriptor/Qualifier:
Carbon Isotopes / chemistry
Hydrogen / chemistry*
Imidazoles / analysis*,  chemistry*
Magnetic Resonance Spectroscopy*
Models, Biological
Chemical
Reg. No./Substance:
0/Carbon Isotopes; 0/Imidazoles; 1333-74-0/Hydrogen

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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