Document Detail


1,4-Bis(p-tolylethynyl)benzene.
MedLine Citation:
PMID:  15750253     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Abstract/OtherAbstract:
The rod-like molecule of the title hydrocarbon, C24H18, is centrosymmetric, with the centroid of the central benzene ring residing on an inversion center. The molecules display a planar conformation of the benzene rings and aggregate into stacks along the [010] direction via Csp(3)-H...pi(arene) interactions, thus forming a stair-like pseudo-two-dimensional network. Each molecule acts as both a C-H hydrogen donor and a pi-arene acceptor, forming four hydrogen bonds per molecule.
Authors:
Alexander S Filatov; Marina A Petrukhina
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Publication Detail:
Type:  Journal Article     Date:  2005-02-28
Journal Detail:
Title:  Acta crystallographica. Section C, Crystal structure communications     Volume:  61     ISSN:  0108-2701     ISO Abbreviation:  Acta Crystallogr C     Publication Date:  2005 Mar 
Date Detail:
Created Date:  2005-03-07     Completed Date:  2006-05-01     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  8305826     Medline TA:  Acta Crystallogr C     Country:  Denmark    
Other Details:
Languages:  eng     Pagination:  o193-4     Citation Subset:  -    
Affiliation:
Department of Chemistry, University at Albany, SUNY, Albany, NY 12222, USA.
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