Document Detail


1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo-[3.3.1.1]decane tetra-fluoro-borate.
MedLine Citation:
PMID:  21201899     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Abstract/OtherAbstract:
The title compound, C(7)H(15)N(3)P(+)·BF(4) (-) or [PTA-Me][BF(4)], is the N-methyl-ated derivative of the well known water-soluble amino-phosphine 1,3,5-triaza-7-phosphaadamantane (PTA). The asymmetric unit consists of a cage-like cation [PTA-Me](+) and a disordered tetra-fluoro-borate anion; two F atoms are disordered equally over two sites. A network of weak inter-molecular C-H⋯F hydrogen bonds results in a three-dimensional supra-molecular assembly.
Authors:
Piotr Smoleński; Alexander M Kirillov; M Fátima C Guedes da Silva; Armando J L Pombeiro
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Publication Detail:
Type:  Journal Article     Date:  2008-02-06
Journal Detail:
Title:  Acta crystallographica. Section E, Structure reports online     Volume:  64     ISSN:  1600-5368     ISO Abbreviation:  Acta Crystallogr Sect E Struct Rep Online     Publication Date:  2008  
Date Detail:
Created Date:  2011-01-04     Completed Date:  2011-07-14     Revised Date:  2013-03-28    
Medline Journal Info:
Nlm Unique ID:  101089178     Medline TA:  Acta Crystallogr Sect E Struct Rep Online     Country:  England    
Other Details:
Languages:  eng     Pagination:  o556     Citation Subset:  -    
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